The Hollywood golden couple split back in 2005 after the hunky actor went off with Ang after meeting her on the set of Mr & Mrs Smith. In an an interview with Vanity Fair at the time of their divorce, Jen admitted she was in a "lengthy period of mourning" after their break-up. Jennifer and Brad's marriage came to an end after five years of being wed, with the Meet Joe Black star immediately going off with Angelina.

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There had been cracks in the relationship, with Brad reportedly annoyed that Jennifer signed up to do a final series of hit comedy Friends. It was during the filming of the finale that Brad met Angelina on the set of Mr and Mrs Smith - with Ang telling Vogue that the two of them simply "became a pair". But the heartbreak that "the pair" left Jen in was likened by the actress to a form of grieving.

She revealed: "There are many stages of grief. It’s sad, something coming to an end. It cracks you open, in a way - cracks you open to feeling. "When you try to avoid the pain, it creates greater pain." Jennifer also revealed the difficulty of having such a high profile split, she went on: "I’m a human being, having a human experience in front of the world. I wish it weren’t in front of the world. "I try really hard to rise above it."

Jennifer and Brad were officially divorced on October 2, 2005. At the time, the official line on the breakup was that it was amicable and they had "exited the relationship as beautifully as they had entered it". This statement was exposed to being possibly false after the couple split, as Brad was in a relationship with Angelina from the moment that the separation was announced, Brad then went on to marry Angelina, but this didn't last, with the pair divorcing this year.